Two babies remain in a serious condition after a crash on the Stuart Highway on Monday evening.
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A family of six was airlifted to Royal Darwin Hospital after their car rolled near Emerald Springs.
A mother remains in a critical state and her 14-month-old daughter is in a serious condition but stable.
It is believed they suffered head injuries.
A six-week-old baby boy is also in a serious condition.
An adult with shoulder and head injuries and an adult with a suspected fractured arm are both in stable conditions.
A 10-year-old girl has been discharged.
CareFlight crews joined forces with first responders and clinic staff from Adelaide River, Pine Creek and Katherine to rescue the family.
The family was travelling south from Darwin to Katherine in a blue Holden Commodore when the car rolled.
Police are calling for anyone who might have witnessed the vehicle before or after the crash to come forward.